Electrochemical Trifluoromethylselenolation of Activated Alkyl Halides
نویسندگان
چکیده
A practical electrochemical method for the generation of CF3Se− anion from a shelf-stable reagent (TsSeCF3) is reported allowing metal-free trifluoromethylselenolation activated alkyl halides. Trifluoromethylselenolated compounds have been obtained in modest to excellent yields under optimized reaction conditions. Finally, cyclic voltammetric and 19F NMR studies are presented allowed gain insight into mechanism.
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ژورنال
عنوان ژورنال: European Journal of Organic Chemistry
سال: 2022
ISSN: ['1434-193X', '1099-0690']
DOI: https://doi.org/10.1002/ejoc.202200123